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Syntheses, Structures, Ionic Conductivities, and Magnetic Properties of Three New Transition-Metal Borophosphates Na 5 (H 3 O){M II3 [B 3 O 3 (OH)] 3 (PO 4 ) 6 }·2H 2 O (M II = Mn, Co, Ni)

✍ Scribed by Yang, Miao; Yu, Jihong; Di, Jiancheng; Li, Jiyang; Chen, Peng; Fang, Qianrong; Chen, Yan; Xu, Ruren


Book ID
121267939
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
217 KB
Volume
45
Category
Article
ISSN
0020-1669

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## Abstract Crystals of Zn(NO~3~)~2~· H~2~O and Mn(NO~3~)~2~· 2 H~2~O were synthesized by heating melts of the respective penta- or hexahydrates. Single crystal X-ray diffraction of the two highly hygroscopic phases reveals new sheet-structure types: Zn(NO~3~)~2~· H~2~O [__Pbca__,__a__= 9.722(1),__