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✦ LIBER ✦
Syntheses, Structures, and Transannular π−π Interactions of Multibridged [3 n ]Cyclophanes 1
✍ Scribed by Sakamoto, Youichi; Miyoshi, Naomi; Hirakida, Mihoko; Kusumoto, Shirou; Kawase, Haruo; Rudzinski, Jerzy M.; Shinmyozu, Teruo
- Book ID
- 126160146
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 501 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0002-7863
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The acid-catalyzed cyclization of a pseudogeminally substituted acetyl group and a chloromethyl group of tri-bridged cyclophane 7 , followed by reduction of the carbonyl group afforded (3,](1,2,3,5)cyclophane 3. One-step TosMIC coupling reaction of tetrabromide 12 and subsequent reduction of the car