Syntheses, structures, and reactivity of poly(pyrazolyl)silanes, -disilanes, and the ambidentate κ1Si/κ3N-coordinating tris(3,5-dimethylpyrazolyl)silanide ligand [Si(3,5-Me2pz)3]− (MeTpsd)

Synthesis and Structure of [Tp*Rh{P(C7H7

Synthesis and Structure of [Tp*Rh{P(C7H7)3}] – Competition between the Ligands Tris(3,5-dimethyl-1-pyrazolyl)borate (Tp*) and Tris(1-cyclohepta-2,4,6-trienyl)phosphane. Proof of the κ2(N,B–H) Coordination Mode of the Tp* Ligand

✍ Max Herberhold; Stefan Eibl; Wolfgang Milius; Bernd Wrackmeyer 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 107 KB 👁 1 views

Stepwise introduction of the potential tripod ligands tris(3,5-dimethyl-1-pyrazolyl)borate (Tp\*) and tris(1cyclohepta-2,4,6-trienyl)phosphane into the coordination sphere of rhodium(I) leads mainly to [Tp\*Rh{P(C 7 H 7 ) 3 }] (4), in which Tp\* is linked to the rhodium through a single pyrazolyl gr