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Syntheses, Structures, and Reactivity of a Series of (Pentamethylcyclopentadienyl)molybdenum(V) and -tungsten(V) Imido Complexes

✍ Scribed by Köhler, Katrin; Roesky, Herbert W.; Herzog, Axel; Gornitzka, Heinz; Steiner, Alexander; Usón, Isabel

Book ID
126121035
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
263 KB
Volume
35
Category
Article
ISSN
0020-1669

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✍ Udo Radius; Juri Attner 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 496 KB 👁 3 views

Syntheses, spectroscopic properties, molecular structures, and LW(NMes)(NCMe) 2b(NCMe) are reported. All complexes contain a group VI metal imido [M=NR] moiety and bonding of novel calix[4]arene imido compounds are described. Treatment of M(NtBu) 2 (NHtBu) 2 Ia (M = Mo), Ib mounted on the phenoxide