Syntheses, Structures, and Magnetic Properties of Two 1D, Mixed-Ligand, Metal Coordination Polymers, [M(C4O4)(dpa)(OH2)] (M = CoII, NiII, and ZnII; dpa = 2,2'-dipyridylamine) and [Cu(C4O4)(dpa)(H2O)]2·(H2O)
✍ Scribed by Chih-Chieh Wang; Cheng-Han Yang; Gene-Hsiang Lee; Hui-Lien Tsai
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 203 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-1948
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## Abstract In this paper, we consider various ways of crystal growth of the polymer [Cu(__µ__ ‐C~2~O~4~)(4‐aminopyridine)~2~(H~2~O)]~n~. Single crystals of the size of 1.5×1.5×0.2 mm^3^ have been grown by a slow diffusion technique from solutions of the monoammine copper complex and of the mixture
New homo-and heterometallic hexanuclear complexes of formula {[Cu(tmen) tetrakis(aminomethylene)methanetetrakis(oxamic acid), tmen = N,N,NЈ,NЈ-tetramethylethylenediamine, pmdien = N,N,N',N',N''-pentamethyldiethylenetriamine, and cyclam = 1,4,8,11-tetraazacyclotetradecane] have been synthesized. The