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Syntheses, structures and electrochemistry of some 1-(η2-allylamino)-1-ferrocenylcarbene complexes of chromium(0), molybdenum(0) and tungsten(0): Part 13: The chemistry of metallacyclic alkenylcarbene complexes

✍ Scribed by Rainer Schobert; Rhett Kempe; Thomas Schmalz; Alexander Gmeiner


Book ID
108189151
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
262 KB
Volume
691
Category
Article
ISSN
0022-328X

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The complex chemical behaviour of 2-phosphaindolizines 1 strong upfield signal (δ 31 P = 6.1) was observed with a coordination shift of ∆δ = -161.7, which is typical for π-(1,3-azaphospholo[1,5-a]pyridines) towards metal carbonyl compounds was studied. (η 1 -2-Phosphaindolizine)M(CO) 5 coordination.