The crystal structure of a copper(II) complex of 2acetylpyridine 3-piperidylthiosemicarbazone, [Cu(Acpip) 2 ], indicates a tridentate, monoanionic ligand (i. e., pyridine nitrogen, imine nitrogen and thiolato sulfur atoms) and a bidentate, monanionic ligand (i. e., imine nitrogen and thiolato sulfur
✦ LIBER ✦
Syntheses, Structures and Coordination Modes of Acetatopalladium(II) Complexes with 1,3-Bis(2-arylimino)isoindoline Ligands of Different Steric Influence
✍ Scribed by Martin Bröring; Christian Kleeberg; Esther Cónsul Tejero
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 208 KB
- Volume
- 2007
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The dinuclear copper(II) complexes {[Cu~2~(1,3‐tpbd)(H~2~O)(OAc)~2~](ClO~4~)~2~}~0.23~{[Cu~2~(1,3‐tpbd)(H~2~O)~2~(OAc)](ClO~4~)~3~}~0.77~·0.77H~2~O (1), [Cu~2~(1,3‐tpbd)(H~2~O)~2~(OAc)~2~](ClO~4~)~2~·2H~2~O (2), and the tetranuclear copper(II) complex [Cu~4~(1,3‐tpbd)~2~(H~2~O)~2~(SO~4~