✦ LIBER ✦
Syntheses, Structures and Characterisation of Two CuII Polymers with 8-Connected Topologies Based on Highly Connected SBUs
✍ Scribed by Jian Zhang; Yao Kang; Jie Zhang; Zhao-Ji Li; Ye-Yan Qin; Yuan-Gen Yao
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 250 KB
- Volume
- 2006
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
Abstract
Two hydrothermally synthesised 3D metal‐coordination polymers, namely [Cu(isonicotinate)(nicotinate)]~n~ (1), with an 8‐connected CsCl topology, and [Cu~2~(μ~3~‐OH)(isonicotinate)~2~(BDC)~0.5~]~n~ (2), with an unusual 8‐connected 3^5^.4^11^.5^8^.6^4^ topology, demonstrate that highly connected SBUs can be employed in the construction of complicated frameworks. The temperature‐dependent magnetic susceptibilities for the two complexes were also determined. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)