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Syntheses, Structure, and Reactivity of 2,6-Dimesitylphenyl-Based Sterically Demanding Gallium Aryls

✍ Scribed by Crittendon, R. Chad; Li, Xiao-Wang; Su, Jianrui; Robinson, Gregory H.

Book ID: 120379035
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 123 KB
Volume: 16
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om970110n

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## Abstract The terdentate aryldiamine ligand in the aryltantalum(V) alkylidene complex [TaCl~2~{C~6~H~3~(CH~2~NMe~2~)~2~‐2,6}(CHBu^t^)] (1) controls alkylidene reactivity in a range of metal‐mediated Wittig reactions. An X‐ray diffraction study of (1) shows that the hexacoordinate tantalum centre