Reaction of cupferron [NH 4 L, L = PhN(O)NO -] with tin(IV), complex 2. The tin centers are heptacoordinated in a pentagonal bipyramidal geometry in the dimeric complex 3. diphenyltin(IV) and dimethyltin(IV) halides yields the cupferronato complexes SnL 4 (1), Ph 2 SnL 2 (2) and These complexes inco
Syntheses, Spectroscopic Studies, and Crystal Structures of Me2Sn(O2PPh2)2, Ph2Pb(O2PMe2)2, and Ph2Pb(O2PPh2)2
✍ Scribed by Abdel-Fattah Shihada; Frank Weller
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- German
- Weight
- 125 KB
- Volume
- 627
- Category
- Article
- ISSN
- 0372-7874
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📜 SIMILAR VOLUMES
H,-elimination from 3 must also occur [Eq. (e)]."ll Note that this equilibrium involves the same 16-electron species implicated in Equation (c). The product-forming hydrido-ethyl (A) and hydridoethyl ethylene (B) species (Scheme 1) "downstream" of reaction (d) have not been observed under a variety
Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure