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Syntheses of tris(pyrazolyl)methane ligands and {[tris(pyrazolyl)methane]Mn(CO)3}SO3CF3 complexes: comparison of ligand donor properties

โœ Scribed by Daniel L. Reger; T.Christian Grattan; Kenneth J. Brown; Christine A. Little; Jaydeep J.S. Lamba; Arnold L. Rheingold; Roger D. Sommer


Book ID
108346670
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
219 KB
Volume
607
Category
Article
ISSN
0022-328X

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Tris(pyrazolyl)methane Ligands: Synthese
โœ Alberto Sรกnchez-Mรฉndez; Gustavoย F. Silvestri; Ernesto deย Jesรบs; F.ย Javier deย laย  ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 197 KB

## Abstract The substituted ligands Me~3~SiC(pz)~3~ (1) and Me~3~SiOCH~2~C(pz)~3~ (2) have been prepared starting from HC(pz)~3~ and HOCH~2~C(pz)~3~. The molecular structure of compound 1 has been determined by Xโ€ray diffraction studies, which show a propellerโ€like conformation of the pyrazolyl rin