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Syntheses of the terpenoid precursors cyclopent-2-enone and cyclohex-2-enone diesters

✍ Scribed by I. Kádas; V. Morvai; G. Árvai; L. Tőke; Á. Szöllősy; G. Tóth; M. Bihari

Book ID
104952828
Publisher
Springer Vienna
Year
1995
Tongue
English
Weight
663 KB
Volume
126
Category
Article
ISSN
0026-9247

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Regiochemical Trends in Intramolecular [2 + 2] Photocycloadditions of 6-(prop-2-enyl)cyclohex-2-enones and 5-(prop-2-enyl)cyclopent-2-enones
✍ Giuliano Cruciani; Paul Margaretha 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 German ⚖ 480 KB

## Abstract The effect of substituents (X  H, Me, or F at C(6), R  H or Me at C(2′) of the allyl side chain) on the photoisomerization (λ = 350 nm) of 6‐allylcyclohex‐2‐enones 1 in MeCN is studied. Substituents X control the overall efficiency of intramolecular [2 + 2] photocycloadduct formation