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Syntheses of the picrotoxane skeleton via the palladium (II) - catalyzed carbacyclization reaction

โœ Scribed by Barry M Trost; David J Jebaratnam

Book ID
104227139
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
179 KB
Volume
28
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The ability of the palladium (+2)-catalyzed intramolecular carbametalation to form quaternary and vicinal quaternary centers in anti-Markovnikov fashion was demonstrated by the syntheses of the picrotoxane skeleton.

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โœ Barry M. Trost; Curt D. Haffner; David J. Jebaratnam; Michael J. Krische; Andrew ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 3 views

The Palladium-Catalyzed Enyne Cycloisomerization Reaction in a General Approach to the Asymmetric Syntheses of the Picrotoxane Sesquiterpenes. Part 1. First-Generation Total Synthesis of Corianin (V) and Formal Syntheses of Picrotoxinin (VIa) and Picrotin (VIb).