A protecting-group-free route to (À)-taiwaniaquinone F based on a ring contraction and subsequent aromatic oxidation of a sugiol derivative is reported. In addition, the first synthesis of (þ)-taiwaniaquinol A is reported via short time exposure of (À)-taiwaniaquinone F to sunlight triggering a remo
✦ LIBER ✦
Syntheses of Taiwaniaquinone F and Taiwaniaquinol A via an Unusual Remote C–H Functionalization
✍ Scribed by Thommen, Christophe; Jana, Chandan Kumar; Neuburger, Markus; Gademann, Karl
- Book ID
- 120019109
- Publisher
- American Chemical Society
- Year
- 2013
- Tongue
- English
- Weight
- 445 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1523-7060
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