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Syntheses of some novel polymers containing the viologen structure and their application to electron-transfer reactions in heterophases

✍ Scribed by Saotome, Yasushi; Endo, Takeshi; Okawara, Makoto

Book ID
120393983
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
492 KB
Volume
16
Category
Article
ISSN
0024-9297

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Viologen polymers (PV 2 ) with carbon chain spacers were prepared by the polymeric reaction with poly(4vinyl pyridine). These polymers were used as an electrontransfer catalyst (ETC) for the reduction of azobenzene, either in a ZnΒ±PV 2 system (reductant: Zn, in CH 3 CN/ H 2 O) or in a Na 2 S 2 O 4 Β±

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## Abstract Several polymers with viologen structure were prepared by polymer analogous reaction with poly(vinyl alcohol) (PVA) and ethylcellulose (EC). The polymers were used as electron‐transfer catalysts (ETC) for the reduction of azobenzene, either in a Zn‐PV^2+^ system (reductant: Zn, in CH~3~