Syntheses of s yndiotactic -Polystyrene- g raft -poly(methyl methacrylate), s yndiotactic -Polystyrene- g raft -poly(methyl acrylate), and s yndiotactic -Polystyrene- g raft - a tactic -polystyrene with Defined Structures by Atom Transfer Radical Polymerization

Synthesis of Polystyrene-block-Poly(meth

Synthesis of Polystyrene-block-Poly(methyl methacrylate) with Fluorene at the Junction: Sequential Anionic and Controlled Radical Polymerization from a Single Carbon

✍ Nathan D. Contrella; Eric S. Tillman; Joshua G. Leasure; Ian W. Monk 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 255 KB

## Abstract Polystyrene‐__block__‐poly(methyl methacrylate) (PS‐__b__‐PMMA) has been synthesized by sequential anionic and reverse atom transfer radical polymerization (ATRP) or a variation of nitroxide mediated polymerization (NMP) from a single initiating site, specifically the 9‐carbon on 2,7‐di