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Syntheses of polychloro-compounds. II: The catalytic action of aluminium chloride in the reaction between chloroform and dichloroethylene

✍ Scribed by H. J. Prins; F. J. W. Engelhard


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
340 KB
Volume
54
Category
Article
ISSN
0165-0513

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The rate of the solvent substitution reaction, CoCl 3 S Γ€ +Cl Γ€ YCoCl 4 2Γ€ +S (S-solvent) has been studied by means of stopped flow spectrophotometry in dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF), and the rate constant k f , and the activation enthalpy D f H p and entropy D f S p have