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Syntheses of Macrocyclic Bis(bibenzyl) Compounds Derived from Perrottetin E

✍ Scribed by Andreas Speicher; Matthias Groh; Markus Hennrich; Anh-Minh Huynh

Book ID: 102829011
Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 718 KB
Volume: 2010
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.201001023

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✦ Synopsis

Abstract

Macrocyclic bis(bibenzyl) compounds are natural products from liverworts and are of growing interest due to recent reports on new isolated compounds and on their remarkable biological activities. We report here on a flexible and general approach to the total set of nine bis(bibenzyl) compounds of the riccardin and plagiochin type derived from perrottetin E. The structures were confirmed through their spectroscopic data, which were compared carefully with those for the isolated products to exclude any errors in arene connection and substitution pattern.

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