Syntheses of (−)-Isocitric Acid Lactone and (−)-Homoisocitric Acid. A New Method of Conversion of Alkynylsilanes into the Alkynyl Thioether and Corresponding Carboxylic Acids
✍ Scribed by Schmitz, Carole; Rouanet-Dreyfuss, Anne-Claire; Tueni, Marie; Biellmann, Jean-François
- Book ID
- 118022225
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 275 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-3263
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Heterocyclic aldehydes such as 2-thiophenecarbaldehyde (1) condense with 3-aroylpropionic acids 2 or their sodium salts to give the enol lactones 3a-d of 3-aroyl-2-(2-thienylmethy-1ene)propionic acids. Isomerization of 3 ad leads to the corresponding 4-arylbenzo[b]thiophene-6-carboxylic acids 4a-d.