✦ LIBER ✦
Syntheses of homologous, tritium-labelled photoaffinity analogs of the natural juvenile hormones JH I, JH II, and JH III
✍ Scribed by István Ujváry; Wai-Si Eng; Glenn D. Prestwich
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- French
- Weight
- 363 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-2135
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Enantiomerically enriched (≥92% e.e.) tritium‐labelled diazoacetate photoaffinity analogs EBDA and EHDA (each 58 Ci/mmol) and EFDA (14 Ci/mmol) were prepared from the corresponding tritiated juvenile hormone (JH) homologs JH I, JH II, and JH III in two steps. Selective reduction of the ester group and subsequent acylation gave the target compounds.