Silsesquioxanes constitute a diverse range of Si-O frameworks with a wide variety of intriguing possibilities as models for catalysis. These topologically interesting molecules are formed by the hydrolytic condensation of trifunctional organosilanes. Heterosilsesquioxanes are formally derived by sub
β¦ LIBER β¦
Syntheses of highly-functionalized polyhedral oligosilsesquioxanes
β Scribed by Frank J. Feher; Theodore A. Budzichowski
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 618 KB
- Volume
- 379
- Category
- Article
- ISSN
- 0022-328X
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A series of polyhedral oligomeric silsesquioxanes (POSS) monomers bearing silane or a-olefin substituents have been prepared and their chemistry explored. Both the POSS silanes and a-olefin monomers readily participate in hydrosilation chemistry and have been used as starting materials for the prepa