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Syntheses of deuterated methyl 9,15-octadecadienoate and methyl 9,12,15-octadecatrienoate geometric isomers

✍ Scribed by Henry Rakoff

Publisher
John Wiley and Sons
Year
1986
Tongue
French
Weight
563 KB
Volume
23
Category
Article
ISSN
0022-2135

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📜 SIMILAR VOLUMES

Synthesis of deuterated methyl 6,9,12-oc
Synthesis of deuterated methyl 6,9,12-octadecatrienoate geometric isomers
✍ Henry Rakoff 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 402 KB

15, 16, 16.d 4 and the corresponding eis.cis, trans isomer were obtained by coupling hexyl-d~-triphenylphosphonium bromide and methyl 12-oxo-cis-6,cis-9-dodecadienoate by the Wittig reaction. The deuterated phosphonium salt was prepared from 3-hexynol by catalytic deuteration of the corresponding

Preparation of cis,cis-, trans,cis-, cis
Preparation of cis,cis-, trans,cis-, cis,trans- and trans,trans-12,15-octadecadienoic-9,10-d2 acids, methyl esters and triglycerides
✍ Henry Rakoff; Edward A. Emken 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 French ⚖ 532 KB

## Abstract Methyl __cis__,__cis__‐, __trans__,__cis__‐, __cis__,__trans__‐, and __trans__,__trans__‐12,15‐octadecadienoates‐9,10‐d~2~ were prepared by the Wittig Reaction between __cis__‐ or __trans__‐3‐hexenyltriphenylphosphonium bromide and methyl 12‐oxododecanoate‐9,10‐d~2~ with butyl lithium i