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Syntheses of Cyclopentanols by a Silicon-Induced Cascade Reaction

✍ Scribed by Michael-Ralph Fischer; Dr. Andreas Kirschning; Dipl.-Chem. Tycho Michel; Prof. Dr. Ernst Schaumann


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
247 KB
Volume
33
Category
Article
ISSN
0044-8249

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Synthesis of 3′-Deoxyribolactones using
✍ Danielle J. Vugts; Halil Aktas; Kanar Al-Mafraji; Frans J. J. de Kanter; Eelco R 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB

## Abstract The synthesis of 3′‐deoxyribolactones was accomplished in a few steps from the commercially available 3‐decyn‐1‐ol in 44 % overall yield. The key transformation comprises a one‐pot four‐reaction hydrolysis‐induced lactonization cascade. The strategy was employed to efficiently access op