Syntheses of chromium(III) complexes with Schiff-base ligands and their catalytic behaviors for ethylene polymerization
β Scribed by Jing-Yu Liu; Yue-Sheng Li; Jing-Yao Liu; Ze-Sheng Li
- Book ID
- 108211607
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 216 KB
- Volume
- 244
- Category
- Article
- ISSN
- 1381-1169
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The reaction of the Schiff bases (obtained by condensing isatin with o-aminophenol/o-aminothiophenol/o-aminobenzoic acid) with [RuX 3 (EPh 3 ) 3 ] (where X = Cl/Br; E = P/As) in benzene afforded new, air-stable Ru(III) complexes of the general formula [Ru(L)X(EPh 3 ) 2 ] (L = dianion of tridentate S
## Abstract Totally sixteen new titanium and zirconium nonβCp complexes supported by Schiffβbase, or thiophene diamide ligands have been synthesized. The complexes are obtained by the reaction of M(OP~T~β__i__)~4~ (M=Ti, Zr) with the corresponding Schiffβbase ligand in 1: 1 molar ratio in good yiel