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Syntheses of chlorins possessing fused nitrogen-containing rings

✍ Scribed by Claire K. Johnson; David Dolphin

Book ID
104259397
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
159 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

Two novel chlorins with fused nitrogen-containing rings were synthesized via a formylmethylimine-substituted octaethylporphyrin. The outcome of the ring-forming reaction was dependent on whether the intermediate was metallated or metal-free.

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## Abstract Five new nitrogen‐oxygen mixed donor macrocycles have been prepared by condensation of 2,6‐bis [(2‐formylphenyl)oxymethyl]pyridine with different diamino compounds in hot methanol, followed by a one‐pot reduction of the intermediate bis‐Schiff base. All the macrocycles were identified b