✦ LIBER ✦
Syntheses of cadinanes. Synthetic correlation of absolute configuration between the cadinane sesquiterpenes and monoterpenes of the p-menthane series
✍ Scribed by Milton D. Soffer; Gűniz Emine Gűnay; Oya Korman; Margie Burt Adams
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- French
- Weight
- 190 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
WE wlah to report an unamblguoue oonrerelon of natural (-Ioryptone (I) to the oryetalllne dloyollo dlketone, II, whloh le obtained ln Its dextrorotatory form and la shown to be the enantlomer of the known otonlzatlon produot' of the native eesqulterpene, c-oadlnene (III). The oanflguratlon ot (-)oryptone har been oorrelated prerlouely with that of the natural monoterpenoldr (-)-a-phellandrene', (-)-plperltol', (-)-plperltone4, (-)-&phellandrenes, and (-)-phellandra16, and the same oorrelatlone have been eetabllehed Independently