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Syntheses of 4-benzyl-3,5-dimethylpyrazolylborato complexes of molybdenum and tungsten nitrosyls: molecular structure of [Mo(CO)2(NO){HB(3,5-Me2-4-PhCH2C3N2)3}], a complex with an ?inverted? bowl-like structure

✍ Scribed by Jeffery, John C.; Kurek, Stefan S.; McCleverty, Jon A.; Psillakis, Elefteria; Richardson, Rob M.; Ward, Michael D.; Wlodarczyk, Andrzej


Book ID
121331753
Publisher
The Royal Society of Chemistry
Year
1994
Tongue
English
Weight
856 KB
Volume
17
Category
Article
ISSN
1472-7773

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Complexes of the (Tetramethylcyclobutadi
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The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th