Syntheses of 3-Phenyl-2H-Azaphosphirene Chromium and Molybdenum Complexes − First Evidence for Reaction Intermediates

✍ Scribed by Rainer Streubel; Frank Ruthe; Peter G. Jones

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 452 KB
• Volume: 1998
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/(sici)1099-0682(199805)1998:5<571::aid-ejic571>3.0.co;2-9

✦ Synopsis

The synthesis of 3-phenyl-substituted 2H-azaphosphirene pentacarbonylchromium and pentacarbonylmolybdenum complexes is reported. New information on the rearrangement cascade, which finally leads to 2H-azaphosphirene ring formation, has been obtained through isolation of a reactive