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Syntheses of 2-substituted 1,N6-ethenoadenosines

✍ Scribed by Yip, Kin-Fai; Tsou, Kwan-Chung

Book ID
118257361
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
545 KB
Volume
40
Category
Article
ISSN
0022-3263

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## Abstract Methylation of 1,__N__^6^‐ethenoadenosine (εAdo) gives a mixture of N1‐ and N9‐quaternized methyl‐3‐β‐D‐ribofuranosylimidazo[2,1‐__i__] purinium salts (m^1^εAdo^+^ and m^9^εAdo^+^, respectively). The ratio of the two forms of the protonated εAdo [H^1^εAdo^+^]/[H^9^εAdo^+^] has been esti