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Syntheses, Crystal Structures, and Spectroscopic and Magnetic Properties of [Mn 2III (H 2 L 1 )(Cl 4 Cat) 4 ·2H 2 O] ∞ and [Mn 2III (H 2 L 2 )(Cl 4 Cat) 4 ·2CH 3 CN·2H 2 O] ∞ : Temperature-Dependent Valence Tautomerism in Solution

✍ Scribed by Shaikh, Nizamuddin; Goswami, Sanchita; Panja, Anangamohan; Sun, Hao-Ling; Pan, Feng; Gao, Song; Banerjee, Pradyot


Book ID
126235200
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
251 KB
Volume
44
Category
Article
ISSN
0020-1669

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✍ Salim F. Haddad; Roger D. Willett; Christopher P. Landee 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 133 KB

The preparation, crystal structure and magnetic properties of the title compound, (1,3-xylylenediammonium)auqatrichlorocuprate(II) chloride hydrate, have been determined. It is monoclinic, space group P2 1 /c, with a=12.711(2), b= 6.122(1), c=19.175(5) A , and i =96.72(2)°with V= 1481.6(5) A , 3 for