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Syntheses, Crystal Structures, and Magnetic Properties of Carboxylate-Bridged Copper(II) Complexes with Bis(2-Pyridylmethyl)Amino Acids

✍ Scribed by Ki-Young Choi; Sun-Young Park; Yong-Man Jeon; Haiil Ryu

Publisher
Springer
Year
2005
Tongue
English
Weight
146 KB
Volume
16
Category
Article
ISSN
1040-0400

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## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~