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Syntheses, Crystal and Solution Structures, Ligand-Exchange, and Ligand-Coupling Reactions of Mixed Pentaarylantimony Compounds

✍ Scribed by Günter Schröder; Takaaki Okinaka; Yasuyuki Mimura; Mitsuko Watanabe; Takayuki Matsuzaki; Atsushi Hasuoka; Yohsuke Yamamoto; Shiro Matsukawa; Kin-ya Akiba

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
394 KB
Volume
13
Category
Article
ISSN
0947-6539

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Encapsulation of Cyanometalates by a Tri
Encapsulation of Cyanometalates by a Tris-macrocyclic Ligand Tricopper(II) Complex: Syntheses, Structural Variation, and Magnetic Exchange Coupling Pathways
✍ Mihail Atanasov; Peter Comba; Yaroslaw D. Lampeka; Gerald Linti; Thomas Malchere 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 572 KB

## Abstract The reaction of [M(CN)~6~]^3−^ (M=Cr^3+^, Mn^3+^, Fe^3+^, Co^3+^) and [M(CN)~8~]^4−/3−^ (M=Mo^4+/5+^, W^4+/5+^) with the trinuclear copper(II) complex of 1,3,5‐triazine‐2,4,6‐triyltris[3‐(1,3,5,8,12‐pentaazacyclotetradecane)] ([Cu~3~(L)]^6+^) leads to partially encapsulated cyanometalat