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Syntheses and X-ray Crystal Structures of Functionalised 9,10-Bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene Derivatives

✍ Scribed by Martin R. Bryce; Terry Finn; Adrian J. Moore; Andrei S. Batsanov; Judith A. K. Howard


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
454 KB
Volume
2000
Category
Article
ISSN
1434-193X

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✦ Synopsis


Dithioles /


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Photochemistry of the π-Extended 9,10-Bi
✍ Allison E. Jones; Christian A. Christensen; Dmitrii F. Perepichka; Andrei S. Bat 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 146 KB

Flash photolysis of bis [4,5di(methylsulfanyl)1,3-dithiol-2-ylidene]-9,10-dihydroanthracene (1) in chloroform leads to formation of the transient radical cation species 1 . which has a diagnostic broad absorption band at l max % 650 nm. This band decays to half its original intensity over a period o