Syntheses and structures of two- and three-dimensional coordination networks generated from silver complexes and hmt (hmt=hexamethylenetetramine)
โ Scribed by Wei-Ming Bu; Ling Ye; Yu-Guo Fan
- Book ID
- 108495759
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 269 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1387-7003
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Interesting two-dimensional networks with square or hexagonal cavities, and three-dimensional networks with different channels, have been obtained by varying the counterions, the molar ratio of metal to hmt (hmt = hexamethylenetetramine) and the pH values of the initial solutions. Among the eleven p
The self-assembly of Cd(II) ion, hexamethylenetetramine(hmt) and maleate ligand yields coordination polymer [Cd 3 with channels, in which Cd(II) ions intercalate between the two-dimensional wavy layers of polymer, joining them as spacers to give a three-dimensional (3, 4)-connected network of uncom