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Syntheses and Structures of Mg(C 5 H 5 BMe) 2 , Mg(3,5-Me 2 C 5 H 3 BNMe 2 ) 2 , the 2,2‘-Bipyridine Adduct Mg(C 5 H 5 BMe) 2 (bipy), and the N-Bonded Aminoboratabenzene Species Mg(3,5-Me 2 C 5 H 3 BNMe 2 ) 2 (THF) 21

✍ Scribed by Zheng, Xiaolai; Englert, Ulli; Herberich, Gerhard E.; Rosenplänter, Jörg


Book ID
126028740
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
99 KB
Volume
39
Category
Article
ISSN
0020-1669

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New Alkali Metal Boratabenzenes: Structu
✍ Xiaolai Zheng; Gerhard E. Herberich 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 195 KB

## Abstract The potassium salt K(C~5~H~5~BMe) (8) can be obtained from 2‐(Me~3~Sn)C~5~H~5~BMe (7)/KO__t__Bu in toluene in essentially quantitative yield. Metalation of 1‐(dimethylamino)‐3‐methylene‐1,2,3,6‐tetrahydroborinine (9) with MN(SiMe~3~)~2~ (M = Na, K) in toluene afforded the unsolvated sal