Syntheses and Structures of Azol-1-yl Derivatives of Nitronyl and Imino Nitroxides.
✍ Scribed by Eugene V. Tretyakov; Galina V. Romanenko; Victor I. Ovcharenko
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 88 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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Several new cobalt(III) complexes incorporating 4,4,5,5tetramethyl-2-(3-or 4-pyridyl)imidazolin-1-oxyl 3-oxide (NITnpy) (n = 3 or 4) or 4,4,5,5-tetramethyl-2-(3-or 4-pyridyl)imidazolin-1-oxyl (IMnpy) have been prepared. The X-ray crystallographic analyses and the spectroscopic investigations have re
## Abstract The crystal structures and magnetic properties of the nitronyl nitroxide radicals 4,5‐dihydro‐4,4,5,5‐tetramethyl‐3‐oxido(1__H__‐imidazol‐1‐yloxyl) (**1**), 4,5‐dihydro‐2,4,4,5,5‐pentamethyl‐3‐oxido(1__H__‐imidazol‐1‐yloxyl) (**2**), 2‐(4‐chlorophenyl)‐4,5‐dihydro‐4,4,5,5‐tetramethyl‐3‐
## Abstract Two novel adducts of formula Mn(hfaC)~2~(NITPhCLI)~2~ (1) and Mn(hfac)2(IMHPhCl)I~2~(NIT‐PhCl) 0.5H~2~O (2), where hfac = hexafluoroacetylacetonate, NITPhCI = 2–(3‐chlorophenyl)‐4,4,5,5‐tetramethylimidazolyl‐1‐oxyl‐3‐oxide, IMHPhCl = 2‐(3‐chlorophenyl)‐4, 4, 5, 5‐tetramethylimidazolyl‐3