𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Syntheses and Structures of 13-Substituted 1,5,9-Triazatricyclo[7.3.1.05,13]-tridecanes and Their Copper(II) Chloride Complexes

✍ Scribed by Köhn, Randolf D. ;Seifert, Guido ;Kociok-Köhn, Gabriele

Publisher
Wiley (John Wiley & Sons)
Year
1996
Tongue
English
Weight
414 KB
Volume
129
Category
Article
ISSN
0009-2940

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The orthoamides 2a, b (R = Ph and PhCH~2~) have been prepared by alkylation of the guanidinium salt 4^+^BPh~4~^−^ with PhNa and PhCH~2~Na, respectively. The crystal structures of the two orthoamides have been determined by X‐ray crystallography. Their reaction with CuCl~2~ gives 1:1 complexes. The crystal structure of the complex with 2a shows a square planar geometry around the copper atom with η^2^‐2a and two chlorides and weak interactions two the third nitrogen atom and a C–H bond of 2a in the axial positions.

📜 SIMILAR VOLUMES

Syntheses and molecular structures of pe
Syntheses and molecular structures of pentaphenoxy-2-, 3-, and 4-pyridylmethoxycyclotriphosphazene and their copper(II) nitrate complexes
✍ Ursula Diefenbach; Petra Adamaszek; Marcel Bloy 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 250 KB 👁 2 views

The reactions of monochloropentaphenoxycyclotriphosphazene with the sodium salts of 2-, 3-, and 4-pyridylmethanol yield the pentaphenoxy-2-, 3-, and 4-pyridylmethoxycyclotriphosphazenes 1, 2, and 3, respectively. The X-ray structure analysis of 1 shows that the molecule consists of a nearly planar s