𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Syntheses and structural characterization of quadruple-bonded complexes Mo2X2Tp2 (X Cl or Br; Tp  HBpz3, pz  pyrazolyl); transformation of η2-Tp to η3-Tp

✍ Scribed by Chang-Tai Lee; Jhy-Der Chen; Lin-Shu Liou; Ju-Chun Wang


Book ID
103112863
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
475 KB
Volume
249
Category
Article
ISSN
0020-1693

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Synthesis and structural characterizatio
✍ Chen-Long Lee; Pang-Yen Yang; Chang-Wei Su; Jhy-Der Chen; Lin-Shu Liou; Ju-Chun 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 151 KB

From a solution prepared by a reaction of Mo 2 (O 2 CCH 3 ) 4 with KTp\* (Tp\*= hydridotris(3,5-dimethylpyrazolyl)borate, HB(Me 2 Pz) 3 ), in diglyme at room temperature followed by addition of excess (CH 3 ) 3 SiBr to the red solution in refluxing THF, the complexes [HB(Me 2 Pz) 3 )BH][Br 3 Mo(m-Br

Structural Characterization and Intramol
✍ Shiro Hikichi; Michito Yoshizawa; Yasuyuki Sasakura; Hidehito Komatsuzaki; Yoshi 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 531 KB

The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.