From a solution prepared by a reaction of Mo 2 (O 2 CCH 3 ) 4 with KTp\* (Tp\*= hydridotris(3,5-dimethylpyrazolyl)borate, HB(Me 2 Pz) 3 ), in diglyme at room temperature followed by addition of excess (CH 3 ) 3 SiBr to the red solution in refluxing THF, the complexes [HB(Me 2 Pz) 3 )BH][Br 3 Mo(m-Br
✦ LIBER ✦
Syntheses and structural characterization of quadruple-bonded complexes Mo2X2Tp2 (X Cl or Br; Tp HBpz3, pz pyrazolyl); transformation of η2-Tp to η3-Tp
✍ Scribed by Chang-Tai Lee; Jhy-Der Chen; Lin-Shu Liou; Ju-Chun Wang
- Book ID
- 103112863
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 475 KB
- Volume
- 249
- Category
- Article
- ISSN
- 0020-1693
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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.