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Syntheses and Spectroscopic Studies of Some Novel Porphyrin-Pyropheophorbide Dimers and Trimers with Fixed Distances

✍ Scribed by Gang Zheng; Ravindra K Pandey; Timothy P Forsyth; Andrei N Kozyrev; Thomas J Dougherty; Kevin M Smith


Book ID
104256737
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
700 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


Syntheses and spectroscopic properties of pyropheophorbide-porphyrindimers and a bis-Pyropheophorbide-porphyrin trimeraredescribed.Fluorescence spectroscopic data of theoligomersrevealthat themacrocyclesin thesystemsareonlyweaklycoupled.O 1997 Elsevier ScienceLtd.


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AbstractÐCondensation of 13 2 -oxopyropheophorbide a 1 with various aromatic diamines under acid-catalyzed conditions afforded a series of novel chlorins with fused quinoxaline or benzimidazole polyaromatic ring systems. This methodology was extended for the preparation of laterally bridged pyropheo