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Syntheses and spectral properties of 2,3,7,8-tetracyano-5,10-dihydrodipyrazino[2,3-b:2′,3′-e]pyrazine

✍ Scribed by Jae-Yun Jaung; Koushi Fukunishi; Masaru Matsuoka

Book ID
102346007
Publisher
Journal of Heterocyclic Chemistry
Year
1997
Tongue
English
Weight
382 KB
Volume
34
Category
Article
ISSN
0022-152X

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✦ Synopsis

Abstract

Base catalized intermolecular cyclization of 2‐amino‐3‐chloro‐5,6‐dicyanopyrazines gave 5,10‐disubsti‐tuted‐2,3,7,8‐tetracyano‐5,10‐dihydrodipyrazino[2,3‐b:2′,3′‐c]pyrazines 11–20. These compounds have rather small molecular size but have strong intramolecular charge‐transfer chromophoric system. They have strong fluorescence in solution and some have fluorescence even in the solid state which are very important to evaluate their electroluminescence property as an emitter for electroluminescence devices. The physical, structural, and electronic properties of these new 2,3,7,8‐tetracyano‐5,10‐dihy‐drodipyrazino[2,3‐b:2′3′‐e]pyrazines were studied using uv‐visible spectroscopy and the Pariser‐Parr‐Pople molecular orbital calculation method.

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ChemInform Abstract: Syntheses and Spect
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Syntheses and Spectral Properties of 2,3,7,8-Tetracyano-5,10dihydrodipyrazino(2,3-b:2',3'-e)pyrazine. -The physical, structural, and electronic properties of the novel title compounds (IV) are studied using UV-visible spectroscopy and molecular orbital calculation methods. -

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v