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Syntheses and Solid-State Structures of Molecular and Extended Silver(I) Complexes of 4-Isocyano-3,5-diisopropylbenzonitrile

✍ Scribed by Ming-Xing Li; Kung-Kai Cheung; Andreas Mayr

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
209 KB
Volume
152
Category
Article
ISSN
0022-4596

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✦ Synopsis

The molecular complexes [Ag(4-CN-3,5-i-Pr 2 -C 6 H 2 CN) 2 ]X, 1 (a, X ‫؍‬ BF 4 ; b, X ‫؍‬ SO 3 CF 3 ), have been prepared by reaction of the respective silver(I) salts with 2 equivalents of the isocyanide in benzene solution. Reaction of 1b with an equivalent amount of AgSO 3 CF 3 in benzene solution gave the extended molecular solid +[Ag(4-CN-3,5-i-Pr 2 -C 6 H 2 CN) 2 ]SO 3 CF 3 , n , 2. The solidstate structures of 1a and 2 have been determined by singlecrystal X-ray crystallography. Compound 1a crystallizes in the triclinic space group P1 with a ‫؍‬ 10.506(2) A s , b ‫؍‬ 12.838(2) A s ,

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