Syntheses and photophysical properties of cyclometallated iridium (III) acetylide complexes
β Scribed by Jun-Zhi Fu; Xu Zhang; Jin-Yun Wang; Li-Yi Zhang; Zhong-Ning Chen
- Book ID
- 116573133
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 326 KB
- Volume
- 22
- Category
- Article
- ISSN
- 1387-7003
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## Abstract This manuscript reports the synthesis and photophysical investigation of a series of Ir^III^ complexes Ir(__C__β§__N__)~2~(__O__β§__O__) which are functionalized in the __para__ position of the pyridine ring by styryl groups substituted with electronβdonor and βacceptor end groups. The sa
## Abstract A series of cationic diiminoiridium(III) complexes [Ir(ppyβ__N__,__C__)~2~(Lβ__N__,__N__)](PF~6~) has been prepared [Hppy = 2βphenylpyridine; L = 4,4β²β__t__Bu~2~dpbpy (1), 4,4β²βMe~2~dpbpy (2), 4,4β²βMe~2~pbpy (3), 4,4β²βMe~2~bpy (4)] and their photophysical and electrochemical properties