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Syntheses and Photochromic Studies of Dithienylethene-Containing Imidazolium Derivatives and Their Reactivity towards Nucleophiles

✍ Scribed by Dr. Gongping Duan; Dr. Nianyong Zhu; Prof. Dr. Vivian Wing-Wah Yam


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
322 KB
Volume
16
Category
Article
ISSN
0947-6539

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## Abstract (Trimethylsilyl)diazomethane (**1‐H**) reacts with __n__BuLi in THF at elevated temperature to afford (previously reported) **1‐Li·^3^/~2~THF**. However, reaction in hexane/TMEDA at low temperature affords instead the __N__‐lithiate Me~3~SiCNNLi·TMEDA (**9**), which is a novel “open” ps