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Syntheses and Molecular Structures of Bis( tert -butylamido)cyclodiphosph(III)azane Cage Complexes of Thallium(I) and Indium(II)

✍ Scribed by Grocholl, Luke; Schranz, Ingo; Stahl, Lothar; Staples, Richard J.


Book ID
127111406
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
94 KB
Volume
37
Category
Article
ISSN
0020-1669

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Bis(amido)cyclodiphosphazanes, cis- [(tBuN-Β΅) (2) and cis- [(tBuN-Β΅) 2 (PNC 4 H 8 NMe) 2 ] (3) were synthesized by treating the corresponding amines with cis-[ClP(tBuN-Β΅) 2 -PCl] (1). The stoichiometric reactions of 2 or 3 with elemental sulfur and selenium afforded the bis-chalcogenides, cis-[(tBu