𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Syntheses and Cyclization Reactions of Bifunctional 1,2-Bis (styryl)benzenes and Some Aza Analogues. Macrocyclic aza compounds. V

✍ Scribed by Carl-Peter Ehrensperger; Manfred Heberlein; Peter Skrabal


Book ID
102857359
Publisher
John Wiley and Sons
Year
1978
Tongue
German
Weight
629 KB
Volume
61
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The syntheses of the bis (styryl)benzenes 4 and 5 and of the aza analogue 3 are described. Diamine 3 and dialdehyde 5 were cyclized to the 14‐membered macrocycles 19 and 27, respectively. Diamine 4 and glyoxal give the 28‐membered macrocycle 28. The cyclizations are discussed.


πŸ“œ SIMILAR VOLUMES


Aspects of Cyclization Reactions of 2,2β€²
✍ Peter Skrabal; Magadalena Hohl-Blumer πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 German βš– 531 KB

## Abstract Cyclization of diamine **5** with phthalaldehyde and of diamine **6** with glyoxal results in formation of the macrocyclic amino alcohol **8** and the rearrangement product **16**, respectively. The properties and stability of **8** and the reactions of **6** with other bifunctional mol

Synthesis and X-Ray Analysis of 2-(2-2H-
✍ Peter Luger; Jerzy Malkowski; Peter Skrabal πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 German βš– 326 KB

## Abstract The title compound **2** was synthesized from the intermediates **3** and **4**. It is identical with the rearrangement product of **1** and glyoxal, of which the X‐ray structure analysis is described.