## Abstract Cyclization of diamine **5** with phthalaldehyde and of diamine **6** with glyoxal results in formation of the macrocyclic amino alcohol **8** and the rearrangement product **16**, respectively. The properties and stability of **8** and the reactions of **6** with other bifunctional mol
β¦ LIBER β¦
Syntheses and Cyclization Reactions of Bifunctional 1,2-Bis (styryl)benzenes and Some Aza Analogues. Macrocyclic aza compounds. V
β Scribed by Carl-Peter Ehrensperger; Manfred Heberlein; Peter Skrabal
- Book ID
- 102857359
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- German
- Weight
- 629 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
The syntheses of the bis (styryl)benzenes 4 and 5 and of the aza analogue 3 are described. Diamine 3 and dialdehyde 5 were cyclized to the 14βmembered macrocycles 19 and 27, respectively. Diamine 4 and glyoxal give the 28βmembered macrocycle 28. The cyclizations are discussed.
π SIMILAR VOLUMES
Aspects of Cyclization Reactions of 2,2β²
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Peter Skrabal; Magadalena Hohl-Blumer
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1976
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John Wiley and Sons
π
German
β 531 KB
Synthesis and X-Ray Analysis of 2-(2-2H-
β
Peter Luger; Jerzy Malkowski; Peter Skrabal
π
Article
π
1977
π
John Wiley and Sons
π
German
β 326 KB
## Abstract The title compound **2** was synthesized from the intermediates **3** and **4**. It is identical with the rearrangement product of **1** and glyoxal, of which the Xβray structure analysis is described.