Syntheses and Crystal Structures of Two Pentaborates, Na3CaB5O10 and Na3MgB5O10.
โ Scribed by Xuean Chen; Ming Li; Jianlong Zuo; Xinan Chang; Hegui Zang; Weiqiang Xiao
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 15 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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Single crystals of Na 3 BaCl 5 .2H 2 O were obtained from saturated aqueous solutions at two different temperatures (27ยฐ C and 32ยฐ C). The crystal size increases with increasing temperature. The crystals obtained were subjected to a systematic morphological, X-ray and thermal analyses. The study of
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Differential scanning calorimetry (DSC) and X-ray diffraction measurements have been performed on pentasodium trihydrogen tetraselenate dihydrate Na 5 H 3 (SeO 4 ) 4 โข2H 2 O and deuterated Na 5 D 3 (SeO 4 ) 4 โข2D 2 O crystals. Any distinct anomaly around 428 K in the DSC curves for both crystals is