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Syntheses and Crystal Structures of Two Novel Zinc(II) Coordination Polymers

✍ Scribed by Jun Tao; Xin Yin; Yun-Bao Jiang; Le-Fu Yang; Rong-Bin Huang; Lan-Sun Zheng

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
188 KB
Volume
2003
Category
Article
ISSN
1434-1948

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✦ Synopsis

Abstract

Two novel zinc(II) coordination polymers, [Zn~3~(μ~3~‐OH)~2~(nip)~2~] (1) and [Zn~2~(nip)~2~(4,4′‐bpy)~3~·(OH~2~)] (2) (H~2~nip = 5‐nitroisophthalic acid, 4,4′‐bpy = 4,4′‐bipyridyl), were obtained by the hydrothermal reactions of zinc nitrate, 5‐nitroisophthalate (nip) (for 1) and zinc nitrate, 5‐nitroisophthalate and 4,4′‐bipyridyl (for 2). Complex 1 displays a two‐dimensional structure that is built from [Zn~3~(μ~3~‐OH)~2~]~n~ chains, while complex 2 is a three‐dimensional structure formed by the interpenetration of two‐dimensional hydrogen‐bonded bilayers. The photoluminescent properties of complex 1 have also been investigated. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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