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Syntheses and crystal structures of iron co-ordination polymers with 4,4′-bipyridine (4,4′-bpy) and 4,4′-azopyridine (azpy). Two-dimensional networks supported by hydrogen bonding, {[Fe(azpy)(NCS)2(MeOH)2]·azpy}n and {[Fe(4,4′-bpy)(NCS)2(H2O)2]·4,4′-bpy}n

✍ Scribed by Noro, Shin-ichiro; Kondo, Mitsuru; Ishii, Tomohiko; Kitagawa, Susumu; Matsuzaka, Hiroyuki


Book ID
120555562
Publisher
The Royal Society of Chemistry
Year
1999
Tongue
English
Weight
322 KB
Volume
10
Category
Article
ISSN
1472-7773

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✍ Yolanda Rodriguez-Martı́n; Catalina Ruiz-Pérez*; Joaquı́n Sanchiz; Francesc Llor 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 147 KB

The copper(II) complex [Cu 2 (mal) 2 (H 2 O) 2 (4,4%-bpy)] (1) (H 2 mal=malonic acid and 4,4%-bpy= 4,4%-bipyridine) has been prepared and its structure determined by single crystal X-diffraction methods. Compound 1 has a two-dimensional square grid network structure. The square grids are stacked par