𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Syntheses and Crystal Structures of Four New Ammoniates with Heptaarsenide (As73-) Anions.

✍ Scribed by Tobias Hanauer; Michael Grothe; Markus Reil; Nikolaus Korber

Publisher
John Wiley and Sons
Year
2005
Weight
18 KB
Volume
36
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Syntheses and Crystal Structures of Four
Syntheses and Crystal Structures of Four New Ammoniates with Heptaarsenide (As) Anions
✍ Tobias Hanauer; Michael Grothe; Markus Reil; Nikolaus Korber πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 522 KB

## Abstract The syntheses and X‐ray single‐crystal low‐temperature structures of the four new ammoniates [Li(NH~3~)~4~]~3~As~7~β‹…NH~3~ (1), [Rb(18‐crown‐6)]~3~As~7~β‹…8 NH~3~ (2), Cs~3~As~7~β‹…6 NH~3~ (3), and (Ph~4~P)~2~CsAs~7~β‹…5 NH~3~ (4) are reported. The compounds were obtained by either direct redu

Syntheses and Crystal Structures of Ammo
Syntheses and Crystal Structures of Ammoniates with the Phenyl-Substituted Polytin Anions Sn2Ph, cyclo-Sn4Ph, and Sn6Ph
✍ Katharina Wiesler; Christof Suchentrunk; Nikolaus Korber πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 German βš– 527 KB

## Abstract The reaction of diphenyltin dichloride with the binary __Zintl__ phase K~4~Sn~9~ in the presence of excess lithium and 18‐crown‐6 in liquid ammonia led to the ammoniate [K(18‐crown‐6)(NH~3~)~2~]~2~Sn~2~Ph~4~ (1). The analogous reaction with K~4~Ge~9~ and potassium in the absence of furt