Syntheses and crystal structures of diorganotin (IV) moieties with 3-hydroxy-2-pyridinecarboxylic acid
β Scribed by Rufen Zhang; Guangru Tian; Chunlin Ma
- Book ID
- 108188081
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 299 KB
- Volume
- 690
- Category
- Article
- ISSN
- 0022-328X
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## Abstract A series of novel triorganotin(IV) complexes of the type [(R~3~Sn)~3~(TMA)]Β·YΒ·L [R = CH~3~, Y = 3CH~3~OH (1); R = CH~3~, Y = 2CH~3~OH (2); R = C~6~H~5~CH~2~ (3); R = __o__βFβC~6~H~4~CH~2~ (4); R = __o__βClβC~6~H~4~CH~2~ (5); R = C~6~H~5~, L = CH~2~Cl~2~ (6); R = C~6~H~5~, L = EtOHΒ·2H~2~
Four organotin complexes with 2,2 -bipyridine-4,4 -dicarboxylic acid, H 2 dcbp: (dcbp)] n 4 have been synthesized. The complexes 1-4 were characterized by elemental, IR, 1 H, 13 C, 119 Sn NMR, and X-ray crystallographic analyses. Crystal structures show that complex 1 is a monomer with one ligand co